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Brevetoxin b synthesis
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Brevetoxin b synthesis


Date:22.06.2017, 23:39 Screen reader users, click here to load entire article. This page uses JavaScript to progressively load the article content as a user scrolls. Screen reader users, click the load entire article button to bypass dynamically loaded article content. Tetrahedron Letters Volume 41, Issue 40, 30 September 2000, Pages 76737676. RIKEN (The Institute of Physical and Chemical Research Wako, Saitama 351-0198, Japan The ABC-ring system of brevetoxin-B was stereoselectively synthesized based on the 6- endo- cyclization of a hydroxy methylepoxide, ring-closing olefin metathesis and SmI2-induced reductive intramolecular cyclization. The total synthesis of brevetoxin B has been achieved recently after a long search for a suitable pathway. This twelve-year odyssey in synthetic organic chemistry was marked by several strategic and tactical routes, and resulted in numerous new synthetic methods. Keywords brevetoxin-B; endo -cyclization; olefin metathesis; radical cyclization; samarium diiodide Copyright 2000 Elsevier Science Ltd. All rights reserved. No articles found. This article has not been cited. Help Help). This article is a behind-thescenes account of the total synthesis of brevetoxin B, from its origins at the University of Pennsylvania to its completion at the University of California, San Diego, and The Scripps Research Institute, La Jolla, California.
Brevetoxin b synthesis


Brevetoxin b synthesis Brevetoxin b synthesis


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